LAB #R.1: COPPER CYCLE
Concentrated nitric acid (HNO3) is severely corrosive, a strong oxidizer, and toxic by ingestion and inhalation. Reactions of nitric acid with metals generate nitrogen dioxide (NO2), a toxic , reddish brown gas. Work with nitric acid only in a fume hood. Copper (II) sulfate and copper (II) nitrate solution are toxic and irritating to skin. Iron (III)chloride and iron (III) nitrate solutions may be skin and body tissue irritants. Zinc nitrate solution is toxic and irritating to body tissue. Zinc sulfate is a mild body tissue irritant. Avoid contact of all chemical with eyes and skin. Wear chemical splash goggles, chemical-resistant gloves, and a chemical resistant apron or lab coat. Please follow all normal laboratory safety guidelines. Wash hands thoroughly with soap and water before leaving the laboratory.
Brass is a generic term for alloys of copper and zinc. In addition to these metals, brass may also contain small amounts of iron, lead, aluminum, and tin. More than 300 different brass alloys are known, with uses ranging from decorative hardware to architectural construction, musical instruments, and electrical switches. The amount of copper in brass affects its color, hardness, ductility, mechanical strength, electrical conductivity, corrosion resistance, etc. Increased amounts of zinc provide the material with improved strength and ductility. If the zinc content of the brass ranges from 32% to 39%, it will have increased hot-working abilities, meaning that it can be shaped or bent easier when the metal is heated, but the cold-working will be limited. If the brass contains over 39% zinc, it will have a higher strength and lower ductility (at room temperature).
The purpose of this lab is to analyze the amount of copper in brass using visible spectroscopy. Brass can be dissolved by reacting it with concentrated nitric acid, which oxidizes the possible metal components of the alloy to their most common ions, Cu2+, Zn2+, and Fe3+. The lab begins with an introductory activity to distinguish among these metal ions using visible speccentration of copper ions in a solution prepared by dissolving brass in nitric acid. Students must investigate the concentration range over which Beer's law is valid and identify the optimum wavelength for analysis.